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| Name | Term |
| Shri Shyam Nandan Mishra | December 1969 to March 1971 |
| Shri M. S. Gurupadaswamy | March 1971 to April 1972 |
| Shri Kamlapati Tripathi | 30/03/1977 to 15/02/1978 |
| Shri Bhola Paswan Shastri | 24/02/1978 to 23/03/1978 |
| Shri Kamlapati Tripathi | 23/03/1978 to 02/04/1978 |
| 18/04/1978 to 08/01/1980 | |
| Shri Lal K. Advani | 21/01/1980 to 07/04/1980 |
| Shri P. Shiv Shanker | 18/12/1989 to 02/01/1991 |
| Shri M. S. Gurupadaswamy | 28/06/1991 to 21/07/1991 |
| Shri S. Jaipal Reddy | 22/07/1991 to 29/06/1992 |
| Shri Sikander Bakht | 07/07/1992 to 10/04/1996 |
| 10/04/1996 to 16/05/1996 | |
| Shri S.B. Chavan | 23/05/1996 to 01/06/1996 |
| Shri Sikander Bakht | 01/06/1996 to 19/03/1998 |
| Dr. Manmohan Singh | 21/03/1998 to 15/06/2001 |
| 15/06/2001 to 22/05/2004 | |
| Shri Jaswant Singh | 03/06/2004 to 05/07/2004 |
| 05/07/2004 to 16/05/2009 | |
| Shri Arun Jaitley | 03/06/2009 to 03/04/2012 |
| 03/04/2012 to 26/05/2014 | |
| Shri Ghulam Nabi Azad | 08/06/2014 to 10/02/2015 |
| 16/02/2015 to 15/02/2021 |